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Technology

The Pyrox Process

Spent nuclear fuel stored in dry casks at a reactor site

The patent-pending Pyrox process recovers uranium and transuranic (TRU) actinides from commercial spent nuclear fuel as purified metal for emerging fast reactors. The U.S. holds more than 95,000 tons of this fuel, growing by about 2,000 tons per year, with no permanent disposal site. The transuranics in today's inventory alone could fuel the U.S. nuclear fleet for 10 years. We believe opening the fuel cycle to oxide spent fuel is a world-changing development — and that's what Pyrox has the promise to achieve.

Four steps — all inside one molten salt process

  1. 01

    Dissolution

    Spent oxide fuel dissolved in LiCl-KCl molten salt.

  2. 02

    Chlorination

    In-situ chlorination of the oxides within the salt.

  3. 03

    Drawdown

    Galvanic electrochemical drawdown recovers U and U/TRU.

  4. 04

    Metallic fuel

    U/TRU metal ready for fast-reactor fuel; salt regenerated.

Inert-atmosphere glovebox workstation with extended rubber gloves, a laptop cart, and a computer terminal in the Utah Pyrometallurgy Laboratory
Inert-atmosphere glovebox for molten-salt research, University of Utah.

What makes Pyrox different

What differentiates Pyrox from the previous state of the art for pyroprocessing is that it achieves complete dissolution of the spent fuel into a molten salt. This circumvents the need to perform electrolytic reduction of oxide to metal followed by electrorefining impure metal to pure metal.

Conventional pyroprocessing

Direct Electrolytic Reducer
Waste form #1
Cathode Processor #1
Electrorefiner
Waste form #2
Waste form #3
Cathode Processor #2

4 major process steps, 3 waste streams

Pyrox

Pyrox Unit
Waste form #1
Cathode Processor #1

2 major process steps, 1 waste stream

Real-time accountability of fissile material

Because Pyrox fully dissolves spent fuel, fissile actinides stay in a single homogeneous liquid rather than spread across multiple solid and liquid phases. That enables accurate, real-time monitoring of fissile inventory — dramatically reducing proliferation risk.

One vessel: dissolution and recovery

It is the transuranic actinides (TRU) in spent light water reactor fuel that are valuable feedstock for making new fuel. In the Pyrox process, the same vessel that dissolves the spent fuel is used to electrochemically recover purified actinides with significantly concentrated TRU.

Schematic of the Pyrox process vessel showing dissolution and electrochemical recovery

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